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chemistry/hexagonal-close-packing

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Hexagonal Close Packing

Explore the hexagonal close-packed structure in metallic crystals. Understand A-B layer stacking, the hexagonal unit cell, and coordination number.

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Key Concepts

Hexagonal Close Packing (HCP)

Atoms stacked in A-B-A-B close-packed layers, achieving 74.05% space efficiency.

Coordination Number 12

Each atom has 12 nearest neighbors: 6 in the same layer, 3 above, and 3 below.

Hexagonal Unit Cell

A primitive hexagonal prism containing 6 atoms (2 formula units).

Understanding Hexagonal Close Packing

**Hexagonal Close Packing (HCP)** is a dense atomic arrangement where atoms occupy 74.05% of the total volume, shared by metals such as Magnesium (Mg), Zinc (Zn), and Titanium (Ti).

The structure is characterized by an alternating **A-B-A-B** stacking sequence of close-packed hexagonal layers, where atoms in the third layer are positioned directly above the atoms in the first layer.

Our interactive crystal viewer demonstrates the **coordination number of 12** and visualizes the geometric relationship between the hexagonal close-packed layers and the primitive hexagonal prism unit cell.

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